A wide range of colors can be created when firing in an electric kiln. All you need are a few glaze bases and commonly found coloring oxides and carbonates.A wide range of colors can be created when firing in an electric kiln. All you need are a few glaze bases and commonly found coloring oxides and carbonates.

 

There are so many wonderful books, websites and even software that feature spectacular glaze formulas; so one may wonder why this article should be introduced to you. The focus of this research was to establish a comprehensive visual library for everyone. Rather than just providing the reader with a few promising glaze formulas, this reference is a guideline. Because it is a guide, there are some test tiles that do not provide immediate use other than the suggestion of what to avoid, or the percentages of certain chemicals that exceed the safe food-serving level, etc., but I believe that this research will be a good tool for those who wish to experiment with, and push the boundaries of, mid-range firing.

 

Many people may be thinking about switching their firing method from high-fire to mid-range. For instance, students who recently graduated and lost access to school gas kilns, people with a day job and those who work in their garage studios, or production potters who are concerned about fuel conservation and energy savings. This reference is intended as a tool for those people to start glaze experimentation at mid-range that can be accomplished with minimal resources.

 


This article was excerpted from Ceramics Monthly magazine’s January 2011 issue.
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There is no guarantee that this chart will work for everyone everywhere, since the variety between the different resources overwhelmingly affects the results, but by examining a few glazes in this chart you can speculate and make informed adjustments with your materials. This is why all the base glazes for this research use only simple materials that are widely available in the US.

 

Base glaze N501 with 5 % cobalt carbonate added

Five years ago, when I was forced to switch to mid-range oxidation firing with an electric kiln, from gas-fueled reduction firing at high temperatures, most of my hard-earned knowledge in high-fire glazes had to be re-examined. Much to my frustration, many earth metal colorants exhibited completely different behaviors in oxidation firing. Also, problems in adhesion were prominent compared to high-fire glazes.

 

The role of oxides and carbonates used for texturing and opacifying were different as well. But compiling the available glazes and analyzing them were not enough. I felt there should be a simple chart with visual results that explained how the oxides and carbonates behave within this firing range. This motivated me to write a proposal for glaze mid-range research to the McKnight Foundation, which generously sponsors a three-month artist-in-residence program at the Northern Clay Center in Minneapolis, Minnesota.

 

Most of the tests presented in these experiments were executed at the Northern Clay Center from October to December in 2009 using clay and dry materials available at Continental Clay Co. The rest of the tests were completed after my residency at my home studio in Washington, Pennsylvania. For those tests, I used dry materials available from Standard Ceramics Supply Co.

 

Glaze base N502 with 1 % chrome oxide added

Glaze base N502 with .1% chrome oxide added

Test Conditions

 

Clay body: Super White (cone 5–9) a white stoneware body for mid-range, commercially available from Continental Clay Co.

Bisque firing temperatures: Cone 05 (1910°F, 1043°C), fired in a manual electric kiln for approximately 10 hours.

Glaze firing temperatures: The coloring metals increment tests (page 50) were fired to cone 5 (2210°F, 1210°C) in a manual electric kiln for approximately 8 hours. The opacifier/texture metals increment tests (page 51) were fired to cone 5 in an automatic electric kiln for 8 hours.

Glaze batch: Each test was 300g, with a tablespoon of epsom salts added as a flocculant.

Glazing method: Hand dipping. First dip (bottom half): 3 seconds. Second dip (top half) additional 4 seconds on top of the first layer, total 7 seconds.

 

Coloring Metals Increment Chart

 

The following colorants were tested: black nickel oxide, cobalt oxide, copper carbonate, chrome oxide, iron chromate, manganese dioxide, red iron oxide, rutile, and yellow ochre. You should note that tests with cobalt oxide and chrome oxide in high percentages were not executed due to the color predictability. Other blank tiles on the chart are because either the predictability or the percentages of oxides are too insignificant to affect the base glazes.

 

Glaze base N503 with 1% black nickel oxide added.

Glaze base N503 with 1% black nickel oxide added.

Depending on firing atmospheres, manganese dioxide exhibits a wide variety of colors. When fired in a tightly sealed electric kiln with small peepholes, the glaze color tends toward brown, compared to purple when fired in a kiln with many and/or large peepholes.

 

Please note that some of the oxides and carbonates in this test exceed the safety standard for use as tableware that comes in contact with food. Check safety standards before applying a glaze with a high percentage of metal oxides to food ware and test the finished ware for leaching.

 

Test tile numbering system: The glaze name is the first part of the identification number, followed by an abbreviation or code that stands for the colorant name. The last part is a two or three digit number referring to the percentage of colorant added.

 

So, for example if a test was mixed with glaze base N501, to which 1 percent cobalt oxide was added, the test tile marking would be: N501COX10.

 

Glaze base 504 with 1% iron chromate added.

Glaze base 504 with 1% iron chromate added.

Conclusion

 

This group of tests has been a great opportunity for me to study the characteristics of oxides and carbonates and how they behave at mid-range temperatures. There are scientific methods for calculating glazes and proven theories, but there are many small pieces of information that can only be picked up when you actually go through the physical experiments. It is important for us to become familiar with a glaze’s behavior so that we can better utilize it. Key to that is learning both the theory and application. It is my hope that these tests will benefit many potters by helping them to expand their palette and inspire them to test the possibilities.

 

the author Yoko Sekino-Bové is an artist living in Washington, Pennsylvania. She would like to thank the McKnight Foundation and the Northern Clay Center and its supporting staff for making this research possible.

 


Cone 5 Glaze Recipes

See below for charts of test tile images showing the result of mixing these glazes with various coloring oxides and carbonates, including copper carbonate, red iron oxide, cobalt oxide, chrome oxide, magnesium dioxide, black nickel oxide, iron chromate, rutile, and yellow ochre. An additional test shows one of the base recipes with added opacifiers and texture metals. All firings were done in an electric kiln, in an oxidation/ neutral atmosphere.

 

N501 (transparent, glossy and crackles)

Ferro Frit 3110 90 %
EPK Kaolin 10 %
Total 100 %

 

 

 

N502 (transparent and glossy)
Gillespie Borate 30 %
F-4 Feldspar 46 %
EPK 13 %
Silica 11 %
Total 100 %

 

 

 

N503 (opaque, glossy
and textured)
Gillespie Borate 52.6 %
EPK Kaolin 21.0 %
Silica 26.4 %
Total 100.0 %
Add: Zircopax 10.0 %
   
N504 (semi-opaque, semi-satin with textures)
Whiting 9.5 %
Ferro Frit 3124 44.5
F-4 Feldspar 20.0
Zinc Oxide 5.5
Bentonite* 7.5
EPK Kaolin 5.0
Silica 8.0
Total 100.0 %
Add: Zircopax 9.0 %
* Bentonite is typically listed as an addition to recipes, but in larger amounts it contributes appreciably to the amount of alumina and silica in the recipe and is therefore included along with the clays in the list of the main ingredients.
N505 (satin, opaque with textures)
(translucent green in reduction, maroon in oxidation)
Dolomite 12 %
Gillespie Borate 14
Wollastonite 10
Ferro Frit 3124 8
Cornwall Stone 46
EPK Kaolin 10
Total 100 %
Add: Magnesium Carbonate 6 %

Charts Showing Colorant Test Results For Glaze Bases N501 (left)
and N502 (right).
Click the chart to see a larger version, or download a PDF version here

 

 


Charts Showing Colorant Test Results For Glaze Bases N503 (left)
and N504 (right). 
Click the chart to see a larger version, or download a PDF version here.

 

 


Chart Showing Colorant Test Results for Glaze Bases N505 (left) and N502 with Added Opacifiers/ Texture Metals (right).
Click the chart to see a larger version, or
for a PDF version, click here

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